You might be able to do that in C. But you'd be wandering into aliasing problems and a hunka hunka burning undefined behavior.
And because struct padding is up to a compiler, what you might get with your memcpy is just ds.member1 = 0xFF, ds.member2 = whatever junk happened to be on the stack at the time, because member1 was padded to occupy 4 bytes rather than just 1. Or maybe you get junk for both, because you set the top 2 bytes of a 4-byte and they're in the bottom 2 bytes.
What you're wandering into is compiler/runtime-specific memory layouts. The same is true in Java. Java itself won't let you do something so horrendously un-Java, but if you write your own JVM or debug an existing JVM written in C or C++, you could do something like that. And who knows what would happen; I'm not Java god enough to know exactly how much the JVM spec pins down JVM implementation, but my guess is, not to the degree necessary to enable interoperability of the in-memory, runtime representations of objects.
So you get undefined behavior in every language flavor. Tastes just as good in each language, too - like mystery meat.
ClassLoader.defineClass.chararray.