Next time, please include the script in your original question in a nice format. It makes helping go faster.
I think it is just a simple mistake. You get theta and phi out of gamma and psi respectively, but then you never use them. Did you mean to use those as your parameters in g? If so, then it should look something like this
from numpy import sin, cos, arange, linspace, pi, zeros
import scipy.optimize as opt
def dG(thetaf, psi, gamma):
return 0.35*(cos(psi))**2*(2*sin(3*thetaf/2+2*gamma)+(1+4*sin(gamma)**2)*sin(thetaf/2)-sin(3*thetaf/2))+sin(psi)**2*sin(thetaf/2)
nt = 100
np = 100
gamma = linspace(0, pi/2, nt)
psi = linspace(0, pi/2, np)
x = zeros((nt, np))
for i, theta in enumerate(gamma):
for j, phi in enumerate(psi):
print('i = %d, j = %d') %(i, j)
g = lambda thetaf: dG(thetaf,phi,theta)
x[i,j] = opt.brenth(g,-pi/2,pi/2)