It's not that it's difficult to have references to objects in clojure; but generally, these references are immutable. It's immutability which makes the doubly linked list impossible, because unlike a singly-linked list, you can't change any part of it without creating a mutation somewhere.
To see this, suppose I have a singly linked list,
a -> b -> c
and suppose I want to change the head of it. I can do so, with changing the entirety of the list. I create a new list by creating a new value for the head value, and reuse the tail:
a'-> b -> c
But doubly linked lists are impossible. So in clojure, and other functional languages, we sometimes use a zipper in such situations.
Now, suppose you really need mutable references in Clojure -- how do it? Well, depending on what concurrency semantics you need, clojure has vars, refs, atoms, etc.
Also, with deftype, you can create objects that have mutable fields, and these mutable fields can hold references to other things. You can also use raw java arrays in clojure for this same purpose.
Is your database going to be an in-memory database, or a disk-backed database? If on disk, I think that the issue of pointer swizzling is trickier than that of having mutable references.
Getting back to the issue of functional data structures, I believe that it is possible to create B-trees which have purely functional semantics. The first clue here is that it's a tree, and trees are the bread butter and meat of functional data structures. Secondly, note that there are databases which work in an append-only fashion -- couchDB for instance. This has the benefit that the database is its own log, in a sense. To get more of an idea of the costs and benefits of this approach you might want to watch Slava Akhmechet's presentation. His company, RethinkDB, eventually took a sort of hybrid approach, IIRC.