You have a problem that python cannot solve.
It sounds like your network has been administratively compartmentalized for some reason. If there is a firewall or a bastion-host machine connected to both administrative domains, you might be able to leverage Port Address Translation to keep this server on one network and poll the other.
If 192.168.192.0 has not been intentionally segmented for administrative / security reasons; it could be a simple oversight by your LAN administrator. In that case, they can add 192.168.192.0 to the corporate routing table.
The final option would be some kind of VPN connectivity between the administrative domains... again, discuss with your network admins.
EDIT
Since you need a linux ethernet alias, the easiest way is with iproute2 in linux... use ip addr add 192.168.192.1/24 dev eth0 as root
[mpenning@Finger ~]$ sudo ip addr add 192.168.192.1/24 dev eth0
[mpenning@Finger ~]$ ip addr show
1: lo: <LOOPBACK,UP,LOWER_UP> mtu 16436 qdisc noqueue state UNKNOWN
link/loopback 00:00:00:00:00:00 brd 00:00:00:00:00:00
inet 127.0.0.1/8 scope host lo
inet6 ::1/128 scope host
valid_lft forever preferred_lft forever
2: eth0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc mq state UP qlen 1000
link/ether 78:2b:cb:0a:8c:f9 brd ff:ff:ff:ff:ff:ff
inet 192.168.12.238/24 brd 192.168.12.255 scope global eth0
inet 192.168.192.1/24 scope global eth0
inet6 fe80::7a2b:cbff:fe0a:8cf9/64 scope link
valid_lft forever preferred_lft forever
[mpenning@Finger ~]$ ip route show
192.168.192.0/24 dev eth0 proto kernel scope link src 192.168.192.1
192.168.12.0/24 dev eth0 proto kernel scope link src 192.168.12.238
default via 192.168.12.236 dev eth0
[mpenning@Finger ~]$
Now plug your printer into your ethernet switch... you should be able to ping 192.168.192.168... to remove: ip addr del 192.168.192.1/24 dev eth0 (as root)