Some wild guesses:
The PHP-version uses different parameters and variables each query: MySQL cannot cache it. While the version you type on the MySQL-CLI uses the same parameter: MySQL can fetch it from its cache. Try adding the SQL_NO_CACHE to your query on CLI to see if the result requires more time.
You are not testing on the same machine? Is the MySQL database you test the PHP-MySQL query with and the CLI the same machine? I mean: you are not testing one on your laptop and the other one on some production server, are you?
You are testing over a network: When the MySQL server is not installed on the same host as your PHP app, you will see some MySQL connection that uses "someserver.tld" instead of "localhost" as database host. In that case PHP will need to connect over a network, while your CLI already has that connection, or connects only local.
The actual connection is taking a long time. Try to run and time the query from your PHP-system a thousand times after each other. Instead of "connect to server, query database, disconnect", you should see the query timing when it is "connect to server, query database thousand times, disconnect". Some PHP-applications do that: they connect and disconnect for each and every query. And if your MySQL server is not configured correctly, connecting can take a gigantic amount of the total time.
explain select.