var url = ....;
var arr = url.split('/');
var value = arr.pop().match(/^(.+)\.html$/)[1];
alert(value); // "s_014654"
Live DEMO
Update: (based of the comment)
<a href="http://company.com/inetucm/groups/public/@enterprise/documents/pagecontent/s_014654.html" />
<a href="http://company.com/inetucm/groups/public/@enterprise/documents/pagecontent/AAAAAAAA.html" />
<a href="http://company.com/inetucm/groups/public/@enterprise/documents/pagecontent/BBB.html" />
<a href="http://company.com/inetucm/groups/public/@enterprise/documents/pagecontent/fdskl489j.html" />
jQuery:
var arr = $('a').map(function(){
return this.href.split('/').pop().match(/^(.+)\.html$/)[1];
}).get();
This will return all the values in an array.
Live DEMO