1. UOPZ
There's a way to do it without having to copy and maintain functions.php file from core, but it involves extension uopz (pecl install uopz), then you can rename magento's function (from foo to foo_uopzOLD for example) and define your own (https://secure.php.net/uopz)
It works and is very useful for magento - usually you'll bump into something you can not change. Uopz is very helpful in such cases.
pros: works ;), you don't have to redo it everytime you update Magento (if you do it right, because inside you still can call foo_uopzOLD so you can assure some backward compatibility... in some cases).
cons: it's little bit implicit
2. Composer post-install-cmd
If you don't like the above, but you use composer you can patch any file you want:
"scripts": {
"post-install-cmd": "patch -p0 < change-core-functions.patch"
}
pros: explicit (when patch fail - composer install fails), and since it's explicit - you can revisit and fix the patch every time you upgrade magento
cons: you have modified core file, so you probably would want to add it to .gitignore
3. Ugly solution (uglier than those above)
If none of the above is possible for you (really, give it a try with composer - there's no excuse for not using it). But when you really can not the only way I can think of
- create app/local/Mage/Core/functions.php
- define this one function you need
- load original /app/core/Mage/Core/functions.php
- surround every function foo() {...} with
if(!function_exists("foo"){
function foo() {...}
}
- hold on to your chair and
eval this SOB ;)