First off, I think it'd be easier to check what you're filling the array with instead of checking the array itself. As the filled array grows, searching it will take longer and longer. Insted, consider:
$array = array_merge($array, $row);
if (in_array('ThisisWhatIneed', $row)
{
break;//leaves the while-loop
}
However, if you're query is returning more data, consider changing it to return what you need, only process the data that needs to be processed, otherwise, you might as well end up with code that does something like:
$stmt = $db->query('SELECT * FROM tbl');
while($row = $stmt->fetch(PDO::FETCH_ASSOC))
{
if ($row['dataField'] === 'username')
{
$user = $row;
break;
}
}
WHERE could help a lot here, don't you think? As well taking advantage of MySQL's specific SELECT syntax, as in SELECT fields, you, need FROM table, which is more efficient.
You may also have noticed that the code above uses PDO, not mysql_*. Why? Simply because the mysql_* extension Is deprecated and should not be used anymore
Read what the red-warning-boxes tell you on every mysql* page. They're not just there to add some colour, and to liven things up. They are genuine wanrings.