Once you invoke a synchronized method, the VM will automatically ask a grant of access for the object on which you are invoking the method. If that is given it will enter the synchronized method. Upon exit til will release this access right. While holding the rights, no-one else is allowed into any synchronized method on the same object, effectively serializing the requests.
does that make sense?
Synchronization is designed to make things thread-safe and avoid race conditions, and this fashion reduce access to at most one thread. There is no way for the program to find out whether two synchronized methods A and B are otherwise connected, so it has the policy of least tolerance.
If you have more synchronization that necessary, e.g. that A and B needs to be mutually exclusive and C and D needs to be mutually exclusive, but not between, say A and C then the advice is typically to modularise your code so A+B goes into one object while C+D goes into another, hence avoiding to step over each others toes