HTTP requests are not as easy as you think they are. First of all this is wrong:
"""POST http://www.example.com/api/site/register/ HTTP/1.1
Host: www.example.com
Connection: keep-alive
...
"""
Each line in HTTP request has to end with CRLF (in Python with \r\n), i.e. it should be:
"""POST http://www.example.com/api/site/register/ HTTP/1.1\r
Host: www.example.com\r
Connection: keep-alive\r
...
"""
Note: LF = line feed = \n is there implicitly. Also you didn't see CR in your fiddler, because it's a white-space. But it has to be there (simple copy-paste won't work).
Also HTTP specifies that after headers there has to be CRLF as well. I.e. your entire request should be:
mydata = """POST http://www.example.com/api/site/register/ HTTP/1.1\r
Host: www.example.com\r
Connection: keep-alive\r
Content-Length: 191\r
X-NewRelic-ID: UAIFVlNXGwEFV1hXAwY=\r
Origin: http://www.example.com\r
User-Agent: Mozilla/5.0 (Windows NT 6.3; WOW64) AppleWebKit/537.36 (KHTML, like Gecko) Chrome/33.0.1750.154 Safari/537.36\r
Content-Type: application/x-www-form-urlencoded; charset=UTF-8\r
Accept: application/json, text/javascript, */*; q=0.01\r
X-Requested-With: XMLHttpRequest\r
X-CSRFToken: CEC9EzYaQOGBdO9HGPVVt3Fg66SVWVXg\r
DNT: 1\r
Referer: http://www.example.com/signup\r
Accept-Encoding: gzip,deflate,sdch\r
Accept-Language: en-GB,en;q=0.8\r
Cookie: sessionid=sessionid; sb-closed=true; arp_scroll_position=600; csrftoken=2u92jo23g929gj2; __utma=912.1.1.2.5.; __utmb=9139i91; __utmc=2019199; __utmz=260270731.utmcsr=google|utmccn=(organic)|utmcmd=organic|utmctr=(not%20provided)\r
\r
username=user&password=password&moredata=here"""
Warning: it should be exactly as I've written. There can't be any spaces in front of each line, i.e. this:
mydata = """POST http://www.example.com/api/site/register/ HTTP/1.1\r
Host: www.example.com\r
Connection: keep-alive\r
...
"""
is wrong.
Side note: you can move mydata to the top, outside of the loop. Unimportant optimization but makes your code cleaner.
Now you've said that the site you are using wants you to hex-encode HTTP request? It's hard for me to believe that (HTTP is a raw string by definition). Don't do that (and ask them to specify what exactly this hex-encoding means). Possibly they've meant that the URL should be hex-encoded (since it is the only hex-encoding that is actually used in HTTP)? In your case there is nothing to encode so don't worry about it. Just remove the .encode('hex') line.
Also Content-Length header is messed up. It should be the actual length of the content. So if for example body is username=user&password=password&moredata=here then it should be Content-Length: 45.
Next thing is that the server might not allow you making multiple requests without getting a response. You should use new.recv(b) where b is a number of bytes you want to read. But how many you should read? Well this might be problematic and that's where Content-Length header comes in. First you have to read headers (i.e. read until you read \r\n\r\n which means the end of headers) and then you have to read the body (based on Content-Length header). As you can see things are becoming messy (see: final section of my answer).
There are probably more issues with your code. For example X-CSRFToken suggests that the site uses CSRF prevention mechanism. In that case your request might not work at all (you have to get the value of X-CSRFToken header from the server).
Finally: don't use sockets directly. Httplib (http://docs.python.org/2/library/httplib.html) is a great (and built-in) library for making HTTP requests which will deal with all the funky and tricky HTTP stuff for you. Your code for example may look like this:
import httplib
headers = {
"Host": "www.example.com",
"X-NewRelic-ID": "UAIFVlNXGwEFV1hXAwY=",
"Origin": "http://www.example.com",
"Connection": "keep-alive",
"User-Agent": "Mozilla/5.0 (Windows NT 6.3; WOW64) AppleWebKit/537.36 (KHTML, like Gecko) Chrome/33.0.1750.154 Safari/537.36",
"Content-Type": "application/x-www-form-urlencoded; charset=UTF-8",
"Accept": "application/json, text/javascript, */*; q=0.01",
"X-Requested-With": "XMLHttpRequest",
"X-CSRFToken": "CEC9EzYaQOGBdO9HGPVVt3Fg66SVWVXg",
"DNT": "1",
"Referer": "http://www.example.com/signup",
"Accept-Encoding": "gzip,deflate,sdch",
"Accept-Language": "en-GB,en;q=0.8",
"Cookie": "sessionid=sessionid; sb-closed=true; arp_scroll_position=600; csrftoken=2u92jo23g929gj2; __utma=912.1.1.2.5.; __utmb=9139i91; __utmc=2019199; __utmz=260270731.utmcsr=google|utmccn=(organic)|utmcmd=organic|utmctr=(not%20provided)"
}
body = "username=user&password=password&moredata=here"
conn = httplib.HTTPConnection("example.com")
conn.request("POST", "http://www.example.com/api/site/register/", body, headers)
res = conn.getresponse()
Note that you don't need to specify Content-Length header.
mydatais exactly the same as the HTTP request you've made above. You don't send any headers (includingPOST http://www.example.com/api/site/register/ HTTP/1.1). Perhaps you should write exactly what you put inmydata. Plus why do you.encode('hex')data? HTTP is a raw string. Finally: you should use some high level library (instead of low level sockets) like this one: docs.python.org/2/library/httplib.html