with a as
(
SELECT student.*,row_number() OVER () as rnum FROM student
)
delete from student where ctid in (select ctid from a where rnum =1) -- the
-- row_number you want
-- to delete
Quoted from PostgreSQL - System Columns
ctid :
The physical location of the row version within its table. Note
that although the ctid can be used to locate the row version very
quickly, a row's ctid will change each time it is updated or moved by
VACUUM FULL. Therefore ctid is useless as a long-term row identifier.
The OID, or even better a user-defined serial number, should be used
to identify logical rows.
Note : I strongly recommend you to use an unique filed in student table.
As per Craig's comment, I'll give another way to solve OP's issue it's a bit tricky
First create a unique column for table student, for this use below query
alter table student add column stu_uniq serial
this will produce stu_uniq with corresponding unique values for each row, so that OP can easily DELETE any row(s) using this stu_uniq
uniquefiled in your table ??