>>> Print ("hello")
SyntaxError: unexpected indent
The first one, you wrote, with a space. Before the print() function if you push to space button ,its SyntaxError.
>>> Print ("hello")
Traceback (most recent call last):
File "<pyshell#2>", line 1, in <module>
Print ("hello")
NameError: name 'Print' is not defined
>>>
Without space button, its NameError because Print function calls with lowercase "p". print().
As you know we starting read documents by left to right, so Python does either. On first case, Python saw the "gap" first then throwed SyntaxError,not NameError and program is crushed. Second one there is no gap so throws NameError.
Edit: Probably you using Python 3x, thats because its a different SyntaxError. You should use parantheses in Python 3x.