Klin's answer is a good (i.e. safe) approach to the question as posed, but it can be simplified:
PostgreSQL's -> operator allows expressions. For example:
CREATE TABLE test (
id SERIAL,
js JSON NOT NULL,
k TEXT NOT NULL
);
INSERT INTO test (js,k) VALUES ('{"abc":"def","ghi":"jkl"}','abc');
SELECT js->k AS value FROM test;
Produces
value
-------
"def"
So we can combine that with row_to_json:
CREATE TABLE test (
id SERIAL,
a TEXT,
b TEXT,
k TEXT NOT NULL
);
INSERT INTO test (a,b,k) VALUES
('foo','bar','a'),
('zip','zag','b');
SELECT row_to_json(test)->k AS value FROM test;
Produces:
value
-------
"foo"
"zag"
Here I'm getting the key from the table itself but of course you could get it from any source / expression. It's just a value. Also note that the result returned is a JSON value type (it doesn't know if it's text, numeric, or boolean). If you want it to be text, just cast it: (row_to_json(test)->k)::TEXT
Now that the question itself is answered, here's why you shouldn't do this, and what you should do instead!
Never trust any data. Even if it already lives inside your database, you shouldn't trust it. The method I've posted here is safe against SQL injection attacks, but an attacker could still set k to 'id' and see a column which was not intended to be visible to them.
A much better approach is to structure your data with this type of query in mind. Postgres has some excellent datatypes for this; HSTORE and JSON/JSONB. Merge your dynamic columns into a single column with one of those types (I'd suggest HSTORE for its simplicity and generally being more complete).
This has several advantages: your schema is well-defined and does not need to change if you add more dynamic columns, you do not need to perform expensive re-casting (i.e. row_to_json), and you are able to take advantage of indexes on your columns (thanks to PostgreSQL's functional indexes).
The equivalent to the code I wrote above would be:
CREATE EXTENSION HSTORE; -- necessary if you're not already using HSTORE
CREATE TABLE test (
id SERIAL,
cols HSTORE NOT NULL,
k TEXT NOT NULL
);
INSERT INTO test (cols,k) VALUES
('a=>"foo",b=>"bar"','a'),
('a=>"zip",b=>"zag"','b');
SELECT cols->k AS value FROM test;
Or, for automatic escaping of your values when inserting, you can use one of:
INSERT INTO test (cols,k) VALUES
(hstore( 'a', 'foo' ) || hstore( 'b', 'bar' ), 'a'),
(hstore( ARRAY['a','b'], ARRAY['zip','zag'] ), 'b');
See http://www.postgresql.org/docs/9.1/static/hstore.html for more details.
select column_name from fubar? What is the real problem you are trying to solve here?