Inserting records into a database has always been the most common reason why I've lost a lot of my hairs on my head!
SQL is great when it comes to SELECT or even UPDATEs but when it comes to INSERTs it's like someone from another planet came into the SQL standards commitee and managed to get their way of doing it implemented into the final SQL standard!
If your table does not have an automatic primary key that automatically gets generated on every insert, then you have to code it yourself to manage avoiding duplicates.
Start by writing a normal SELECT to see if the record(s) you're going to add don't already exist. But as Robert implied, your table may not have a primary key because it looks like a LOG table to me. So insert away!
If it does require to have a unique record everytime, then I strongly suggest you create a primary key for the table, either an auto generated one or a combination of your existing columns.
Assuming the first five combined columns make a unique key, this select will determine if your data you're inserting does not already exist...
SELECT COUNT(*) AS FoundRec FROM [Emp_table].[ACT].[LIST_EMP]
WHERE [ENTITY] = wsEntity AND [TYPE] = wsType AND [EMP_COD] = wsEmpCod AND [DATE] = wsDate AND [LINE_NO] = wsLineno
The wsXXX declarations, you will have to replace them with direct values or have them DECLAREd earlier in your script.
If you ran this alone and recieved a value of 1 or more, then the data exists already in your table, at least those 5 first columns. A true duplicate test will require you to test EVERY column in your table, but it should give you an idea.
In the INSERT, to do it all as one statement, you can do this ...
INSERT INTO [Emp_table].[ACT].[LIST_EMP]
([ENTITY],[TYPE],[EMP_COD],[DATE],[LINE_NO],[ACT],[NAME])
VALUES
('REG','EMP','45233','2016-06-20 00:00:00:00','2','SKATING','JANE')
WHERE (SELECT COUNT(*) AS FoundRec FROM [Emp_table].[ACT].[LIST_EMP]
WHERE [ENTITY] = wsEntity AND [TYPE] = wsType AND
[EMP_COD] = wsEmpCod AND [DATE] = wsDate AND
[LINE_NO] = wsLineno) = 0
Just replace the wsXXX variables with the values you want to insert.
I hope that made sense.