I'm configuring a Magento 1.9.1 to use an external SMTP to send emails, using SMTP PRO (https://www.magentocommerce.com/magento-connect/smtp-pro-email-free-custom-smtp-email.html).
I've setup the configuration (hostname, port, username, password) but when I try to send a test email it fails with a 'Could not open socket' error message. If I dig into the code I see that the error is generated from this piece of code in lib/Zend/Mail/Protocol/Abstract.php:
$this->_socket = @stream_socket_client($remote, $errorNum, $errorStr, self::TIMEOUT_CONNECTION);
if ($this->_socket === false) {
if ($errorNum == 0) {
$errorStr = $remote.' Could not open socket '.phpversion();
}
/**
* @see Zend_Mail_Protocol_Exception
*/
#require_once 'Zend/Mail/Protocol/Exception.php';
throw new Zend_Mail_Protocol_Exception($errorStr);
}
My PHP environment (5.6.30) has openssl support (see image and snippet below)

[root@ns3023903 httpdocs]# php -r 'print_r(stream_get_transports());'
Array
(
[0] => tcp
[1] => udp
[2] => unix
[3] => udg
[4] => ssl
[5] => sslv3
[6] => sslv2
[7] => tls
)
There are no firewall issues as i can both telnet on the port 465 to the target host or send an email using the same SMTP using phpmailer with the same user I use to run the site virtualhost.
I'm on a CentOS 7 64 bit server, with SELinux disabled and, if that matters, I'm using Plesk 12 to configure virtual hosts.
Name resolution is also working ok (I can ping the SMTP name correctly and the IP address is looked up just fine).
I'm obviously missing something here...but what?