If you open the database (click it's name in the left hand column), there will be a "Create new table on database dbname" section. Enter the name of the table you want (e.g. hashes), and the number of fields you want.
This is where we need a bit more information: if you just want to store hashes and hashes alone then you'll need two fields: a unique hash ID (of type integer, with auto_increment set to true) and a 32 character text field. I'm a little unsure of the utility of this, so if you post a bit more information we might be able to help you out with what you're trying to achieve a little better?
Edit:
In that case, you'll need three fields: a hash id (a unique reference for each entry in the table), the hash, and the plaintext to which it correlates. Set the hash id to be an integer, with auto_increment set to true. Set the field for the hash to be varchar of length 32, and the plaintext field to 'text'.