In your example string you have characters that need escaping: " and \
fmt.Println("\"C:\\Program Files\\Sublime Text 3\\sublime_text.exe\" C:\\Users\\User\\Desktop\\Guess.py")
You can also use back quotes to create what is called a raw string which doesn't require escaping those characters.
fmt.Println(`"C:\Program Files\Sublime Text 3\sublime_text.exe" C:\Users\User\Desktop\Guess.py`)
List of escapes:
\a U+0007 alert or bell
\b U+0008 backspace
\f U+000C form feed
\n U+000A line feed or newline
\r U+000D carriage return
\t U+0009 horizontal tab
\v U+000b vertical tab
\\ U+005c backslash
\' U+0027 single quote (valid escape only within rune literals)
\" U+0022 double quote (valid escape only within string literals)
See the official docs.
`for string literals