I was searching for the opposite command, to unsubscribe a user manually from powershell due to an external user receiving the emails for a group that were unnecessary to send externally.
Here are the powershell commands, connected to Exhange Online Powershell version 2:
View subscribers:
Get-UnifiedGroupLinks -Identity <email address> -LinkType Subscribers
Add subscribers:
Add-UnifiedGroupLinks -Identity <email address> -LinkType Subscribers -Links <comma separated list of email addresses>
Remove subscribers:
Remove-UnifiedGroupLinks -Identity <email address> -LinkType Subscribers -Links <comma separated list of email addresses>
Documentation