When you are using char *h, you are declaring a pointer to a char variable. This pointer keeps the address of the variable it points to.
In simple words, as you simply declare a char variable as char num='h', then the variable num will hold the value h and so if you print it using printf("%c",num), you will get the output as h.
But, if you declare a variable as a pointer, as char *num, then it cannot actually hold any character value. I can hold only the address of some character variable.
For example look at the code below
void main()
{
char a='h';
char *b;
b=&a;
printf("%c",a);
printf("%c",b);
printf("%u",b);
}
here , we have one char variable a and one char pointer b. Now the variable a may be located somewhere in memory that we do not know. a holds the value h and &a means address of a in memory The statement b=&a will assign the memory address of a to b. Since b is declared as a pointer, It can hold the address.
The statenment printf("%c",b) will print out garbage values.
The statement printf("%u",b) will print the address of variable a in memory.
so there's difference between char num and char *num. You must first read about pointers. They are different from normal variables and must be used very carefully.