Direct answer
To the best of my knowledge, in the specific case you are describing, scan will be marginally slower (esp. in first response). This is when assuming you do not do any filtering (i.e., FilterExpression is empty).
Further thoughts
DynamoDB can potentially store huge amounts of data. By "huge" I mean "more than can fit in any machine's RAM". If you need to 'return all elements of a table' you should ask yourself: what happens if that table grows such that all elements will no longer fit in memory? you do not have to handle this right now (I believe that as of now the table is rather small) but you do need to keep in mind the possibility of going back to this code and fixing it such that it addresses this concern.
questions I would ask myself if I were in your position:
(1) can I somehow set a limit on the number of items I need to read (say,
read only the first 1000 items)?
(2) how is this information (the list of
items) used? is it sent back to a JS application running inside a
browser which displays it to a user? if the answer is yes, then what
will the user do with a huge list of items?
(3) can you work on the items one at a time (or 10 or 100 at a time)? if the answer is yes then you only need to store one (or 10 or 100) items in memory but not the entire list of items
In general, in DDB scan operations are used as described in (3): read one item (or several items) at a time, do some processing and then moving on to the next item.