This is the code I would use. I'm not going to assume your knowledge of HTML/CSS, so here goes:
HTML:
<ul id="navigation">
<li class="home"><a href="#" title="Home">Home</a></li>
<li class="car"><a href="#" title="Car">Car</a></li>
<li class="mobile"><a href="#" title="Mobile">Mobile</a></li>
<li class="old"><a href="#" title="OldThings">OldThings</a></li>
</ul>
CSS:
#navigation {
list-style: none;
margin: 0;
padding: 0;
}
#navigation li {
float: left;
}
#navigation li a {
display: block;
padding: 50px 20px 20px;
}
You will also need to add your image (seen over the 'Home' item) - which I would suggest as a background image, on the "a" tag.
If you do want the "Home" link to be on a different level as the others, you can simply change the "home"'s class to be something like this:
#navigation li.home a {
display: block;
padding: 60px 20px 10px;
}
Just adjust the padding on the "a" style, to match where you want each element (as I have guessed :) ). You'll also have to add colours, and hover states.
Good luck!