Since you're asking about efficiency, the most efficient yet functional approach I can think of is using foldLeft and foldRight.
You need foldRight since :: constructs the immutable list in reverse.
someMap.foldRight(List.empty[(String, String, String)]) { case ((a, m), acc) =>
m.foldRight(acc) {
case ((b, c), acc) => (a, b, c) :: acc
}
}
Here, assuming Map.iterator.reverse is implemented efficiently, no intermediate collections are created.
Alternatively, you can use foldLeft and then reverse the result:
someMap.foldLeft(List.empty[(String, String, String)]) { case (acc, (a, m)) =>
m.foldLeft(acc) {
case (acc, (b, c)) => (a, b, c) :: acc
}
}.reverse
This way a single intermediate List is created, but you don't rely on the implementation of the reversed iterator (foldLeft uses forward iterator).
Note: one liners, such as someMap.flatMap(x => x._2.map(y => (x._1, y._1, y._2))) are less efficient, as, in addition to the temporary buffer to hold intermediate results of flatMap, they create and discard additional intermediate collections for each inner map.
UPD
Since there seems to be some confusion, I'll clarify what I mean. Here is an implementation of map, flatMap, foldLeft and foldRight from TraversibleLike:
def map[B, That](f: A => B)(implicit bf: CanBuildFrom[Repr, B, That]): That = {
def builder = { // extracted to keep method size under 35 bytes, so that it can be JIT-inlined
val b = bf(repr)
b.sizeHint(this)
b
}
val b = builder
for (x <- this) b += f(x)
b.result
}
def flatMap[B, That](f: A => GenTraversableOnce[B])(implicit bf: CanBuildFrom[Repr, B, That]): That = {
def builder = bf(repr) // extracted to keep method size under 35 bytes, so that it can be JIT-inlined
val b = builder
for (x <- this) b ++= f(x).seq
b.result
}
def foldLeft[B](z: B)(op: (B, A) => B): B = {
var result = z
this foreach (x => result = op(result, x))
result
}
def foldRight[B](z: B)(op: (A, B) => B): B =
reversed.foldLeft(z)((x, y) => op(y, x))
It's clear that map and flatMap create intermediate buffer using corresponding builder, while foldLeft and foldRight reuse the same user-supplied accumulator object, and only use iterators.
someMap.flatMap { case (a, m) => m.map { case (b, c) => (a, b, c) } }?for { (a, m) <- someMap; (b,c) <- m } yield (a,b,c)?