ASP.NET Button controls render as:
<input type="submit">
You will need to give them a css class name that you can control in your css file.
In server side code:
myButton.CssClass = "myClass"
OR in ASPX markup:
<asp:Button CssClass="myClass" runat="server" ... />
CSS:
.myClass { width: 100px }
Edit having seen your comment:
To modify all buttons across the site you need to use Javascript, the jQuery library is extremely effective at this. If you were using jQuery you would just have this script on your Master page:
$(document).ready(function()
{
// Select all "input" controls with the type of "submit" and add your class to them
$(input[type="submit"]).addClass('myClass');
});
name=""attribute, it's class, it's ID or what? Also, use something like Firebug or Chrome's DOM inspector to see what the generated HTML looks like, and base your selectors from there. You should try a lowercasebuttonselector - see if that works.