i have a dataframe data and csv data as following

i want to append the dataframe data to the csv file.however ,there are duplicates between the two data.so how to remove the duplicates and append new data to csv file.
I think you need read_csv with DataFrame.append, then drop_duplicates and last to_csv:
pd.read_csv('file').append(df).drop_duplicates().to_csv('file')
to_csv instead of to_file :)